Ages: Jolie, 35; Pitt, 47
Previous TIME 100 appearances: 5
Who knew this couple would last so long? Or our obsession with them their looks, their roles, their passel of children? But despite the Brangelina bling, this couple has invested even more time in charitable work. As a U.N. goodwill ambassador, Jolie most recently visited Pakistan after the country's devastating floods to put a spotlight on the country's victims. And even as Pitt continues to star in phenomenal movies (Inglourious Basterds, for one), he has been relentless in keeping the rebuilding of New Orleans in the news, raising more than $20 million for the area to date.
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